Creating metallic face with cat eyes

Start by opening an image of a model with a focused face.
Duplicate the layer. Press Ctrl+Shift+U to desaturate.
Press Ctrl+M to open curves window. Apply settings as shown.
Select and duplicate the background layer. Select duplicate layer. From image menu select "Apply Image". Select the layer we created in previous step.
Hide the gray layer.
Change the layer mode to "Lighten".
Create selection of the eyeballs using polygon lasso tool. Press Ctrl+J to copy paste the selection in a new layer.
Press Ctrl+U to open hue/saturation window. Apply settings as shown.
 



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